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Chapter 8 - Chemical Bonding - Flashcards

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Class:CHEM 1211 - Principles of Chemistry I
Subject:Chemistry
University:Gainesville State College
Term:Fall 2011
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ionic bond An ionic bond is a type of chemical bond formed through an electrostatic attraction between two oppositely charged ions.
covalent bond A covalent bond is a form of chemical bonding that is characterized by the sharing of pairs of electrons between atoms.
octet rule

Atoms tend to gain, lose, or share electrons until they are surrounded by eight valence elctrrons.

consist of full s and p subshells

ionization energy

Indicates how easily an electron can be removed from an atom.

first ionization energy is the energy needed to remove the first electron. the second ionization energy is the energy needed to removed the second electron...etc.

the GREATER the ionization energy, the more difficult it is to remove an electron because the more energized electrons are pulling towards the nucelus.

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electron affinity

measures how easily an atom can gain an electron.

 

lattice energy

The lattice energy of an ionic solid is a measure of the strength of bonds in that ionic compound.

- the L energy increases as the charge increases.

- the L energy increases as their ionic size decreases.

TO ORGANIZE IONS IN INCREASING OR DECREASING L. ENERGY:

1.first determine the charges on their ions (refer to the back of the book).

2. if some of the ions are equal, arrange them in ionic size.  the smaller the ion, the more L. energy is has.

lewis structure (nonmetals)

the number of valance elctrons in a nuetral atom is the same as the group number.

 

Lewis structure

must fulfill octect rule

draw valance elctrons first

then draw bonds

each atom must have 8 e- (other than H)

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Dmitri Mendeleev

Arranged elements in order of increasing atomic weight.

-Forerunner of the periodic table.

- Given credit for predicting Ga and Ge.

Lothar Meyer did the same thing in Germeny.

Henry Moseley

developed the concept of atomic numbers.

- he found the each element produces a frequency and that frequncey increases as the atomic mass increases.

- he correcrtly identified that the atomic number is the same as the number of protons in the atom.

 

bonding atomic radius

he distance separating the nucleii of two atoms in a molecule.

-the bonding atomic radius is shorter than the nonbonding atomic radius.

how to determine atomic radii

the bonding atomic radii is 1/2 of the bonding distance.

 

radius INCREASES going down a column.

(because the outter elctrons are farther from the nucleus, giving the atoms a larger size)

radius INCREASES going right of a row.

(because the increasing effective nuclear charge draws the electrons closer to the nucleus, giving the atoms a smaller size.)

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cations are _____ than their parent atoms.

smaller - because of the loss of elctrons decreases their atomic radii.

 

 

 

anions are ______ than their parents atoms. larger - because the gain of elctrons increases their atomic radii.
isoelectric series

a groups of ions all having the same number of elctrons.

TO ARRANGE THESE IONS: place the ions in order of increasing atomic number.

The radius of an ion______with______nuclear charge. The radius of an ion DECREASES with INCREASING nuclear charge.
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Ionization energy (periodic table)

In a ROW,  the energy increases with increasing atomic number (moving right).

In a COLUMN, the energy decreases with increasing atomic number (moving down)

Smaller atoms have (higher/lower) ionization energy. HIGHER
The energy needed to remove an elctron from the outermost shell depends on:

effective nuclear charge

and

average distance of the electron from the nucleus.

When electrons are removed to form a cation, they are always removed from the largest n.
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electron affinitiy measures the ease at which an atom can ___ an electron. GAIN
ionization energy measures the ease at which an atom can____ an electron. LOSE
Meats conduct: heat and electricty
metals are ____ at room temp.

solid

 

(except mercury)

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Metals have____ionization energies. LOW
Metals form (cations/anions) easily. CATIONS
Metals are(reduced/oxidized) when they undergo chem rxns.

OXIDIZED

(lose electrons)

Compounds of metals with nonmetals are: ionic substances
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Metal oxides are BASIC. They dissolve in water to form: metal hydroxides
Metal oxides react with acids to form: a salt and water.
Nonmetals are poor conducters of: heat and electricity.
Nonmetals (gain/lose) electrons when they react with metals. gain
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Compounds composed of nonmetals are_____ substances. molecular
Nonmetal oxides are: acidic
Group 1A: alkali metals

1. low densities

2. low metling points

3. lowest ionization energy

4. very reactive to lose an electron to form a cation

5. exsist in nature as compounds only.

6. these metals directly combine with nonmetals.

7. act vigorously with water to produce hydrogen gas and hydroxide solution.

8.when O reacts with these metals, O2- is formed.

9. metal oxides react with water to form hydroxide ions

10. emits a characteristic color when placed in a flame.

Compounds the form the superoxide ion (O2-): Potassium, rubidium, cesium.
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H^-

Hydride.

(When hydrogen gains an electron)

Group 2A: alkaline earth metals

1. solid at room temp

2. less reactive than group 1A

3. Be and Mg ar ethe lightest and less reactive.

4. tend to lose outter shell electrons and form 2+ cations.

5. the heavier the metals give off  colors when under a flame.

6. fireworks: emit colors from group 2A elements.

Hydrogen

1. does not lose it's valence electron easily.

2. shares it's electron with nonmetals and forms molecular compounds

3. able to form covalent bonds

4. able to form metal hydroxides

5. able to lose an electron to form a 1+ cation (H+)

Group 6A: Oxygen Group

1. colorless at room temp

2. O3: ozone

3.great tendency to attract electrons

4. sulfur has a tendendy to gain electrons also.

 

 

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allotropes different forms of the same element in the same state.
Group 7A: halogens

1. salt formers

2. nonmetals

3. melting and boiling points increase with increasing atomic number

4. diatomic molecules

5. highly negative electron affinities

6. tend to gain electrons to form halide ions

7. Cl is the most useful halogen

8. all soluble in water

Group 8A: noble gases

1. all nonmetals, gas at room temp

2. monatomic

3. largest ionization energy

4. unreactive

 

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 ionic bondAn ionic bond is a type of chemical bond formed through an electrostatic attraction between two oppositely charged ions.
 covalent bondA covalent bond is a form of chemical bonding that is characterized by the sharing of pairs of electrons between atoms.
 octet rule

Atoms tend to gain, lose, or share electrons until they are surrounded by eight valence elctrrons.

consist of full s and p subshells

 ionization energy

Indicates how easily an electron can be removed from an atom.

first ionization energy is the energy needed to remove the first electron. the second ionization energy is the energy needed to removed the second electron...etc.

the GREATER the ionization energy, the more difficult it is to remove an electron because the more energized electrons are pulling towards the nucelus.

 electron affinity

measures how easily an atom can gain an electron.

 

 lattice energy

The lattice energy of an ionic solid is a measure of the strength of bonds in that ionic compound.

- the L energy increases as the charge increases.

- the L energy increases as their ionic size decreases.

TO ORGANIZE IONS IN INCREASING OR DECREASING L. ENERGY:

1.first determine the charges on their ions (refer to the back of the book).

2. if some of the ions are equal, arrange them in ionic size.  the smaller the ion, the more L. energy is has.

 lewis structure (nonmetals)

the number of valance elctrons in a nuetral atom is the same as the group number.

 

 Lewis structure

must fulfill octect rule

draw valance elctrons first

then draw bonds

each atom must have 8 e- (other than H)

 Dmitri Mendeleev

Arranged elements in order of increasing atomic weight.

-Forerunner of the periodic table.

- Given credit for predicting Ga and Ge.

Lothar Meyer did the same thing in Germeny.

 Henry Moseley

developed the concept of atomic numbers.

- he found the each element produces a frequency and that frequncey increases as the atomic mass increases.

- he correcrtly identified that the atomic number is the same as the number of protons in the atom.

 

 bonding atomic radius

he distance separating the nucleii of two atoms in a molecule.

-the bonding atomic radius is shorter than the nonbonding atomic radius.

 how to determine atomic radii

the bonding atomic radii is 1/2 of the bonding distance.

 

radius INCREASES going down a column.

(because the outter elctrons are farther from the nucleus, giving the atoms a larger size)

radius INCREASES going right of a row.

(because the increasing effective nuclear charge draws the electrons closer to the nucleus, giving the atoms a smaller size.)

 cations are _____ than their parent atoms.

smaller - because of the loss of elctrons decreases their atomic radii.

 

 

 

 anions are ______ than their parents atoms.larger - because the gain of elctrons increases their atomic radii.
 isoelectric series

a groups of ions all having the same number of elctrons.

TO ARRANGE THESE IONS: place the ions in order of increasing atomic number.

 The radius of an ion______with______nuclear charge.The radius of an ion DECREASES with INCREASING nuclear charge.
 Ionization energy (periodic table)

In a ROW,  the energy increases with increasing atomic number (moving right).

In a COLUMN, the energy decreases with increasing atomic number (moving down)

 Smaller atoms have (higher/lower) ionization energy.HIGHER
 The energy needed to remove an elctron from the outermost shell depends on:

effective nuclear charge

and

average distance of the electron from the nucleus.

 When electrons are removed to form a cation, they are always removed from the largest n. 
 electron affinitiy measures the ease at which an atom can ___ an electron.GAIN
 ionization energy measures the ease at which an atom can____ an electron.LOSE
 Meats conduct:heat and electricty
 metals are ____ at room temp.

solid

 

(except mercury)

 Metals have____ionization energies.LOW
 Metals form (cations/anions) easily.CATIONS
 Metals are(reduced/oxidized) when they undergo chem rxns.

OXIDIZED

(lose electrons)

 Compounds of metals with nonmetals are:ionic substances
 Metal oxides are BASIC. They dissolve in water to form:metal hydroxides
 Metal oxides react with acids to form:a salt and water.
 Nonmetals are poor conducters of:heat and electricity.
 Nonmetals (gain/lose) electrons when they react with metals.gain
 Compounds composed of nonmetals are_____ substances.molecular
 Nonmetal oxides are:acidic
 Group 1A: alkali metals

1. low densities

2. low metling points

3. lowest ionization energy

4. very reactive to lose an electron to form a cation

5. exsist in nature as compounds only.

6. these metals directly combine with nonmetals.

7. act vigorously with water to produce hydrogen gas and hydroxide solution.

8.when O reacts with these metals, O2- is formed.

9. metal oxides react with water to form hydroxide ions

10. emits a characteristic color when placed in a flame.

 Compounds the form the superoxide ion (O2-):Potassium, rubidium, cesium.
 H^-

Hydride.

(When hydrogen gains an electron)

 Group 2A: alkaline earth metals

1. solid at room temp

2. less reactive than group 1A

3. Be and Mg ar ethe lightest and less reactive.

4. tend to lose outter shell electrons and form 2+ cations.

5. the heavier the metals give off  colors when under a flame.

6. fireworks: emit colors from group 2A elements.

 Hydrogen

1. does not lose it's valence electron easily.

2. shares it's electron with nonmetals and forms molecular compounds

3. able to form covalent bonds

4. able to form metal hydroxides

5. able to lose an electron to form a 1+ cation (H+)

 Group 6A: Oxygen Group

1. colorless at room temp

2. O3: ozone

3.great tendency to attract electrons

4. sulfur has a tendendy to gain electrons also.

 

 

 allotropesdifferent forms of the same element in the same state.
 Group 7A: halogens

1. salt formers

2. nonmetals

3. melting and boiling points increase with increasing atomic number

4. diatomic molecules

5. highly negative electron affinities

6. tend to gain electrons to form halide ions

7. Cl is the most useful halogen

8. all soluble in water

 Group 8A: noble gases

1. all nonmetals, gas at room temp

2. monatomic

3. largest ionization energy

4. unreactive