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Past Exam for CHM 2210 - Organc Chem I with Moon at Florida International (FIU)

Exam Information

Material Type:Exam 2
Professor:Moon
Class:CHM 2210 - Organc Chem I
Subject:Chemistry
University:Florida International University
Term:Spring 2010
Keywords:
  • Explanation
  • Diastereomer
  • Dehydration
  • Relationship
  • Diastereomers
  • No Molecules
  • Enantiomers
  • Following Sequence
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Sample Document Text

Midterm 2.  Part II CHM 2210, 2010 Spring, Moon    1    [6 pts] 1. Consider the following pair of structures.   A) Designate each chirality center as (R) or (S) and   B) identify the relationship between them by describing them as representing enantiomers,  diastereomers, constitutional isomers, or two molecules of same compound.    S, S    R,S  Diastereomer        [9 pts] 2. Provide the structure of A, B, and C, of the following sequence of reactions.  No mechanistic  explanation is required.  A CH 3 CH 2 Br B H 2 C NH 3 (l) Ni 2 B [P-2] NaNH 2           Midterm 2.  Part II CHM 2210, 2010 Spring, Moon    2    [10 pts] 3. When 5-chloro-1-pentanol is treated with sodium hydride in diethyl ether, the product is  analyzed to be C 5 H 10 O.  Propose a likely structure for this product, suggesting a reasonable mechanistic  pathway for its formation.  Cl OH NaH Cl O Na + ?H 2 O NaCl .. .. .. .. :           [10 pts] 4. Provide mechanistic explanation ...

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