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Lecture Notes for CHEM 3410 - PHYSICAL CHEMISTRY I with Richard at The Richard Stockton College of New Jersey (StoCo)

Notes Information

Material Type:Class Note
Professor:Richard
Class:CHEM 3410 - PHYSICAL CHEMISTRY I
Subject:Chemistry
University:The Richard Stockton College of New Jersey
Term:Fall 2008
Keywords:
  • Natural Sciences
  • Approximation
  • Experimental Data
  • Concentration
  • Steady State
  • Assumptions
  • Rate Constants
  • To
  • at (time)
  • The Independent
  • Independent
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The Richard Stockton College of New Jersey Chemistry Program, School of Natural Sciences and Mathematics PO Box 195, Pomoma, NJ CHEM 3410: Physical Chemistry I | Fall 2008 November 17, 2008 Lecture 32: More on reaction mechanisms & steady state References 1. Levine, Physical Chemistry, Chapter 16 Key Concepts In consecutive or series reactions, a reactant, A forms an intermediate B, which then forms the product C. { The solution for [A](t) was arrived at using the rst order kinetics we discussed previously. The rate at which [A] decreases depends on the rate constant of the A!B reaction, k1. { The time dependence of [B] can be obtained by solving a di erential equation similar to the case for parallel reactions. [C] can be found by evoking mass conservation. { The rate limiting step will determine the observed concentration behavior for A, B, and C. It is determined by the relative values of k1 and k2. In a reversible reaction, we can arrive at a relationship between rate constants and the...

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